Kinetics and Mechanism of the Chlorine Dioxide-Tetrathionate Reaction
✍ Scribed by Horváth, Attila K.; Nagypál, István; Epstein, Irving R.
- Book ID
- 126126064
- Publisher
- American Chemical Society
- Year
- 2003
- Tongue
- English
- Weight
- 113 KB
- Volume
- 107
- Category
- Article
- ISSN
- 1089-5639
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📜 SIMILAR VOLUMES
The reaction has been studied spectrophotometrically monitoring the absorbance in the wavelength range. The spectra of the reactants, intermediates, and prod-240-400 nm ucts in this system are overlapping; thus special programs [1,2] have been used (and tested) to unravel the kinetics and mechanism
The stoichiometry and kinetics of the oxidation of thiourea (SC(NH2)z) by chlorine dioxide (ClOz) have been studied by uv-vis spectrophotometry using conventional and stopped-flow mixing techniques at 25.0 ? O.l"C, pH 0.3-4.8. In high acid and initial 10 : 1 molar ratio of thiourea to chlorine dioxi