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Kinetics and mechanism of the oxidation of reducing sugars by osmium tetroxide in alkaline medium

โœ Scribed by Hari S. Singh; Arti Gupta; Anil K. Singh; Bihari Singh

Book ID
110340880
Publisher
Springer
Year
1998
Tongue
English
Weight
553 KB
Volume
23
Category
Article
ISSN
0340-4285

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๐Ÿ“œ SIMILAR VOLUMES

Mechanism of oxidation of reducing sugar
Mechanism of oxidation of reducing sugars by osmium tetraoxide in alkaline medium by the stopped-flow technique
โœ Hari Shankar Singh; Bihari Singh; Anil Kumar Singh ๐Ÿ“‚ Article ๐Ÿ“… 1991 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 473 KB

The kinetics of reduction of osmium tetraoxide by L-sorbose, I,-galactose. D-xylose, and L-arabinose in aqueous alkaline medium exhibit a pseudo-unimolecular rate with respect to [osmium tetraoxide]. First-order kinetics were observed with respect to both [sugar] and [OH-] at their lower concentrati