Kinetics and mechanism of the oxidation of amino acids by peroxomonosulphate. Part 2. Effect of formaldehyde
β Scribed by Ramachandram, M. Shanmugan; Vivekanandam, T. Subburamiyer; Raj, R. Patrick Malim Mani
- Book ID
- 120584809
- Publisher
- Royal Society of Chemistry
- Year
- 1984
- Tongue
- English
- Weight
- 476 KB
- Volume
- 8
- Category
- Article
- ISSN
- 1472-779X
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π SIMILAR VOLUMES
The kinetics of the oxidation of aliphatic aldehydes, formaldehyde, acetaldehyde, propionaldehyde, n-butyraldehyde, and trichloroacetaldehyde by Peroxomonosulphate (PMS) was carried out in aqueous perchloric acid medium (0.1-1 M H+) a t constant ionic strength of 1.2 M in the temperature range 1O"-6
The kinetics of the reaction between nitric acid and formaldehyde have been studied by spectrophotometry. The reaction is autocatalytic. A two-step mechanism is proposed, which accounts for this behavior and describes the effect of reactant concentrations on the characteristics of the kinetic curves