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Kinetics and mechanism of the oxidation of amino acids by peroxomonosulphate. Part 1

✍ Scribed by Ramachandran, M. Shanmugam; Vivekanandam, T. Subburamiyer


Book ID
120575182
Publisher
Royal Society of Chemistry
Year
1984
Tongue
English
Weight
401 KB
Volume
8
Category
Article
ISSN
1472-779X

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πŸ“œ SIMILAR VOLUMES


Kinetics and mechanism of oxidation of a
✍ Rajalingam Renganathan; Pichai Maruthamuthu πŸ“‚ Article πŸ“… 1986 πŸ› John Wiley and Sons 🌐 English βš– 461 KB

The kinetics of the oxidation of aliphatic aldehydes, formaldehyde, acetaldehyde, propionaldehyde, n-butyraldehyde, and trichloroacetaldehyde by Peroxomonosulphate (PMS) was carried out in aqueous perchloric acid medium (0.1-1 M H+) a t constant ionic strength of 1.2 M in the temperature range 1O"-6

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## Abstract Oxidation of aromatic amines (substrate) by peroxomonosulphate (PMS) in phthalate buffers at various temperatures revealed first‐order dependence on [PMS] as well as [Substrate]. Rate of oxidation was found to increase with an increase in pH as well as dielectric constant (D) of the med

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## Abstract Kinetics of oxidation of indole‐3‐acetic acid (IAA) by peroxomonosulphate (PMS) in aqueous acetonitrile medium has been investigated. The reaction follows a total second order, first order each with respect to [IAA] and [PMS]. The rate of the reaction was not affected by added [H^+^]. V