Kinetics and mechanism of the oxidation of amino acids by peroxomonosulphate. Part 1
β Scribed by Ramachandran, M. Shanmugam; Vivekanandam, T. Subburamiyer
- Book ID
- 120575182
- Publisher
- Royal Society of Chemistry
- Year
- 1984
- Tongue
- English
- Weight
- 401 KB
- Volume
- 8
- Category
- Article
- ISSN
- 1472-779X
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The kinetics of the oxidation of aliphatic aldehydes, formaldehyde, acetaldehyde, propionaldehyde, n-butyraldehyde, and trichloroacetaldehyde by Peroxomonosulphate (PMS) was carried out in aqueous perchloric acid medium (0.1-1 M H+) a t constant ionic strength of 1.2 M in the temperature range 1O"-6
## Abstract Oxidation of aromatic amines (substrate) by peroxomonosulphate (PMS) in phthalate buffers at various temperatures revealed firstβorder dependence on [PMS] as well as [Substrate]. Rate of oxidation was found to increase with an increase in pH as well as dielectric constant (D) of the med
## Abstract Kinetics of oxidation of indoleβ3βacetic acid (IAA) by peroxomonosulphate (PMS) in aqueous acetonitrile medium has been investigated. The reaction follows a total second order, first order each with respect to [IAA] and [PMS]. The rate of the reaction was not affected by added [H^+^]. V