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Kinetics and Mechanism of the IO + ClO Reaction

✍ Scribed by Bedjanian, Yuri; Le Bras, Georges; Poulet, Gilles

Book ID: 126246569
Publisher: American Chemical Society
Year: 1997
Tongue: English
Weight: 222 KB
Volume: 101
Category: Article
ISSN: 1089-5639
DOI: 10.1021/jp963947p

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The bimolecular rate constant for the reaction Cl + 03 -Cl0 + O2 is measured over the temperature range 210 to 360 K in it dischare flow system using Cl nfom rcsonzncc fluorescence at 134-72 nm to monitor the decay of Cl under pseudo fist order conditions. Results, expressed in the form k, = (2.35 i