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Kinetics and mechanism of the homopolycondensation of DI-β,β′-chloroethylphosphorous acid

✍ Scribed by S.M. Shner; I.K. Rubtsova; Ye.L. Gefter

Book ID
118357723
Publisher
Elsevier Science
Year
1966
Weight
220 KB
Volume
8
Category
Article
ISSN
0032-3950

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The sulfuric acid-catalysed reaction of 1,6-anhydro+D-glucopyranose in lbutanol at SO" gave butyl a-and P-D-glucopyranoside as the sole products. The initial kinetic alp ratio was 1.5, and the final a//3 ratio upon equilibration was 2.7. The four pseudo-first-order reaction rate constants involved h