## Abstract The kinetics of the thermal decomposition reaction of gaseous 3,3,6,6‐tetramethyl‐1,2,4,5‐tetroxane (ACDP) in the presence of __n__‐octane was studied in the 403.2–523.2 K temperature range. This reaction yields acetone as the organic product. Under optimum conditions, first‐order kinet
Kinetics and mechanism of the gas-phase thermal decomposition of cis-2-methylcyclopropane methanol
✍ Scribed by Nisar, Jan ;Ali, Mukhtiar ;Awan, Iftikhar Ahmad
- Publisher
- Springer
- Year
- 2008
- Tongue
- English
- Weight
- 118 KB
- Volume
- 95
- Category
- Article
- ISSN
- 0133-1736
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract Rates of thermal gas‐phase elimination of eleven 2‐aryloxyacetic acid have been measured over a 45°C temperature range for each compound. Hammett correlation of the present kinetic data with the literature σ^0^ values of the given substituents gave a reaction ρ constant of 0.69 at 600 K
## Abstract The gas phase elimination kinetics of 2‐bromopropene was studied over the temperature range of 571–654 K and pressure range of 12–46 Torr using the seasoned static reaction system. Propyne was the only olefinic product formed and accounted for >98% of the reaction. This product was form
## Abstract The mechanism of the gas‐phase elimination kinetics of 2‐ethoxypyridine has been studied through the electronic structure calculations using density functional methods: B3LYP/6‐31G(d,p), B3LYP/6‐31++G(d,p), B3PW91/6‐31G(d,p), B3PW91/6‐31++G(d,p), MPW1PW91/6‐31G(d,p), MPW1PW91/6‐31++G(d,
## Abstract The kinetics and mechanisms of the gas‐phase elimination reactions of neopentyl chloride and neopentyl bromide have been studied by means of electronic structure calculations using density functional methods: B3LYP/6‐31G(d,p), B3LYP/ 6‐31++G(d,p), MPW1PW91/6‐31G(d,p), MPW1PW91/6‐31++G(d
The decomposition kinetics of ethylsilane under shock tube conditions (P, ca. 3100 torr, T = 1080-1245 K), both in the absence and presence of silylene trapping agents (butadiene and acetylene) are reported. Arrhenius parameters under maximum butadiene inhibition are: log K(C,H,SiH,) = 15.14-64,769