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Kinetics and mechanism of the ene reaction of dimethyl mesoxalate with alkenes

โœ Scribed by Achmatowicz, Osman; Szymoniak, Jan

Book ID
126439745
Publisher
American Chemical Society
Year
1980
Tongue
English
Weight
657 KB
Volume
45
Category
Article
ISSN
0022-3263

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The rate constant of the reaction of OH with DMS has been measured relative to OH + ethene in a 420 1 reaction chamber a t 760 torr total pressure and 298 t 3 K in N L + 0, buffer gas using the 254 nm photolysis of H202 as the OH source. In agreement with a recent absolute rate determination of the