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Concertedness in the thermal intermolecular ene reactions of dimethyl mesoxalate and substituted alkenes

โœ Scribed by Jenner, Gerard; Papadopoulos, Mihalis


Book ID
126911033
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
535 KB
Volume
47
Category
Article
ISSN
0022-3263

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The thermal reactions of endoand ao-5-cyanobicyclo-[2.2.2loct-2-ene and their transand cis-6-methyl-substituted derivatives have been investigated in the gas phase between 518 and 630 K. Each product decomposes by two parallel first-order retro-Diels-Alder reactions, a main one with formation of cyc