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Do rotational barriers dictate the regioselectivity in the ene reactions of singlet oxygen and triazolinedione with alkenes?

โœ Scribed by Orfanopoulos, Michael; Stratakis, Manolis; Elemes, Yiannis; Jensen, Frank


Book ID
126972885
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
271 KB
Volume
113
Category
Article
ISSN
0002-7863

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The ene reactions of N-phenyl-l.2,4-triazoline-3S-dione (p'f'AD)and singlet oxygen (102) with tetrrrsubstihrted sfkenes,follow regioselectivitytrendsgovernedmairrtyby 1,3-non bondedinteractions(typeI) for the case of ITAD, and mainfyby the steric hindrancecausedduringthe formationof the new doublebo