Ene reaction of triazolinediones with alkenes. 2. Kinetics and substituent effects
โ Scribed by Ohashi, Shinichi; Butler, George B.
- Book ID
- 124066243
- Publisher
- American Chemical Society
- Year
- 1980
- Tongue
- English
- Weight
- 595 KB
- Volume
- 45
- Category
- Article
- ISSN
- 0022-3263
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
The ene reaction of tiazolinedione with unsymmetrical cis-alkenes is regiospecific and shows a preferential abstraction of the allylic hydrogens on the larger alkyl group of the double bond. ## Triazolinedione (PTAD) undergoes the same type of reactions as singlet oxygen (102). It reacts rapidly
Ene reaction / Manes, vinyl-/ Triazolinediones / Cycloaddition / Regioselectivity / Diastereoselectivity The ene reaction of 4-methyl-l,2,4-triazoline-3,5-dione stereoselectivity. For the former we invoke preferential clea-(MTAD) with vinylsilanes 1 has been investigated. In all cases vage of the C