Cationic polymerizations of trioxane in 1,2-ethylene dichloride and benzene were heterogeneous and reversible. Phase separation accompanying with crystallization occurred during the polymerization. Three morphological changes were found in the course of the polymerization as were investigated by dil
Kinetics and Mechanism of the Cationic Polymerization of Trioxane. III. Copolymerization with Cyclic Formals
โ Scribed by Yeong-Tarng Shieh; Meei-Ling Lay; Show-An Chen
- Book ID
- 111556642
- Publisher
- Springer
- Year
- 2003
- Tongue
- English
- Weight
- 161 KB
- Volume
- 10
- Category
- Article
- ISSN
- 1022-9760
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๐ SIMILAR VOLUMES
The occurrence of hydride-transfer reactions during the cationic polymerization of trioxane was demonstrated, and rate constants were obtained. The donor of hydride ions in the transfer reactions was the monomer. The hydride-transfer reaction was a first-order reaction with respect to the concentrat
The cationic copolymerization of trioxane with butylglycidylether in nitrobenzene was investigated. The rates of exhaustion of the monomers during the copolymerization process were followed by gas chromatography. The effects of temperature and of the content of the catalyst BF,Et,O on the rate of co