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Effect of the reaction medium on the kinetics and mechanism of the cationic polymerization and copolymerization of cyclic ethers

✍ Scribed by G.V. Korovina; D.D. Novikov; D.Ya. Rossina; T.V. Grinevich; N.G. Taganov; R.A. Barzykina; G.N. Komratov; S.G. Entelis

Book ID
118965196
Publisher
Elsevier Science
Year
1976
Weight
370 KB
Volume
18
Category
Article
ISSN
0032-3950

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Cationic polymerizations of trioxane in 1,2-ethylene dichloride and benzene were heterogeneous and reversible. Phase separation accompanying with crystallization occurred during the polymerization. Three morphological changes were found in the course of the polymerization as were investigated by dil