𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Kinetics and Mechanism of the Addition of Nucleophiles to α,β-Unsaturated Thiol Esters

✍ Scribed by Hartman, Rosemarie F.; Rose, Seth D.

Book ID
125931345
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
181 KB
Volume
71
Category
Article
ISSN
0022-3263

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

The mechanism of hydroxylamine addition
The mechanism of hydroxylamine addition to α, β-unsaturated esters
✍ K.R. Fountain; Robert Erwin; Terry Early; Horst Kehl 📂 Article 📅 1975 🏛 Elsevier Science 🌐 French ⚖ 232 KB

The addition of&-nucleophiles to unsaturated substrates has recently drawn both theoretical1 and experimental attention. 2 In this report we present data pertaining to the addition ofd-nucleophiles to Cr,$ -unsaturated esters, in particular ethyl cinnamate. We 'lWe h ave also obtained oils having h

Enantioselective Organocatalytic Conjuga
Enantioselective Organocatalytic Conjugate Addition of Aldehydes to α,β-Unsaturated Thiol Esters
✍ Shaolin Zhu; You Wang; Dawei Ma 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 184 KB 👁 1 views

## Abstract The first example of an organocatalytic asymmetric Michael addition of aldehydes to α,β‐unsaturated thiol esters promoted by chiral diphenylprolinol silyl ether is presented. The reaction occurs with good yields, diastereoselectivity and excellent enantioselectivity.

ChemInform Abstract: Addition of Thiols
ChemInform Abstract: Addition of Thiols to α,β-Unsaturated Esters in the Presence of Alumina.
✍ Yoshitada Suzuki; Goroh Saitoh; Satoru Nawa; Mitsuo Kodomari 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 34 KB 👁 1 views

Addition of Thiols to α,β-Unsaturated Esters in the Presence of Alumina. -Michael-type additions of thiols to α,β-unsaturated esters in the presence of neutral alumina proceed easily under appropriate mild conditions to give the corresponding adducts [cf. (III), (VI)/(VII)] in good to excellent yie