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The mechanism of hydroxylamine addition to α, β-unsaturated esters

✍ Scribed by K.R. Fountain; Robert Erwin; Terry Early; Horst Kehl

Publisher
Elsevier Science
Year
1975
Tongue
French
Weight
232 KB
Volume
16
Category
Article
ISSN
0040-4039

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✦ Synopsis

The addition of&-nucleophiles to unsaturated substrates has recently drawn both theoretical1 and experimental attention.

2 In this report we present data pertaining to the addition ofd-nucleophiles to Cr,$ -unsaturated esters, in particular ethyl cinnamate. We 'lWe h ave also obtained oils having high frequency IR bands at 1780 cm:' from R=ET and C7H15 -hydroxyl amines. 12 Ref. 7 indicates the position of absorption for a conjugated carbonyl in the -C-O-N situation to be 13Ref. 1 d.

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