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Kinetics and mechanism of silver(I)-catalysed oxidation of malonic acid by peroxodiphosphate in acetate buffers

โœ Scribed by Indu Rao; Amita Agrawal; Som K. Mishra; Prem D. Sharma


Publisher
Springer
Year
1993
Tongue
English
Weight
412 KB
Volume
18
Category
Article
ISSN
0340-4285

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A kinetic study of the silver(1)-catalyzed oxidation of tris(1,lO-phenanthroline)iron(II) with peroxodiphosphate was carried out by estimating tris-complex at 510 nm. The reaction is found to conform to the rate law (i). with K2 and K3 being the acid dissociation constants of H~P208-and H~Pz082-, r

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The kinetics of oxidation of some neutralized โฃ-hydroxy compounds such as glycolic (GA), lactic (LA), โฃ-hydroxyisobutyric(IB), mandelic (MA), atrolactic (AL), and benzilic (BA) acids by tetrachloroaurate(III) have been studied. The substrates are oxidized to give formaldehyde, acetaldehyde, acetone,