Kinetics and mechanism of silver(I)-catalysed oxidation of malonic acid by peroxodiphosphate in acetate buffers
โ Scribed by Indu Rao; Amita Agrawal; Som K. Mishra; Prem D. Sharma
- Publisher
- Springer
- Year
- 1993
- Tongue
- English
- Weight
- 412 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0340-4285
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๐ SIMILAR VOLUMES
A kinetic study of the silver(1)-catalyzed oxidation of tris(1,lO-phenanthroline)iron(II) with peroxodiphosphate was carried out by estimating tris-complex at 510 nm. The reaction is found to conform to the rate law (i). with K2 and K3 being the acid dissociation constants of H~P208-and H~Pz082-, r
The kinetics of oxidation of some neutralized โฃ-hydroxy compounds such as glycolic (GA), lactic (LA), โฃ-hydroxyisobutyric(IB), mandelic (MA), atrolactic (AL), and benzilic (BA) acids by tetrachloroaurate(III) have been studied. The substrates are oxidized to give formaldehyde, acetaldehyde, acetone,