Kinetics and mechanism of the ruthenium(III)-catalysed oxidation of aliphatic acids by peroxodiphosphate in acetate buffers
β Scribed by V. Srisailam; M. Anand Rao
- Publisher
- Springer
- Year
- 1994
- Tongue
- English
- Weight
- 359 KB
- Volume
- 19
- Category
- Article
- ISSN
- 0340-4285
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π SIMILAR VOLUMES
A kinetic study of the silver(1)-catalyzed oxidation of tris(1,lO-phenanthroline)iron(II) with peroxodiphosphate was carried out by estimating tris-complex at 510 nm. The reaction is found to conform to the rate law (i). with K2 and K3 being the acid dissociation constants of H~P208-and H~Pz082-, r
## Abstract The oxidative cleavage of some aliphatic ketoximes by thallium(III) acetate was studied in the temperature range of 20β40Β°C. The reactions were followed by determination of the rates of disappearance of thallium(III) acetate for variations in [substrate], [Tl(III)], [H^+^], ionic streng