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Kinetics and mechanism of Ru(III) and Hg(II) co-catalyzed oxidation of d-galactose and d-ribose by N-bromoacetamide in perchloric acid

โœ Scribed by Ashok Kumar Singh; Vineeta Singh; Ajaya Kumar Singh; Neena Gupta; Bharat Singh

Book ID
108309325
Publisher
Elsevier Science
Year
2002
Tongue
English
Weight
206 KB
Volume
337
Category
Article
ISSN
0008-6215

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Mechanism of Pd(II) and Hg(II) co-cataly
Mechanism of Pd(II) and Hg(II) co-catalyzed oxidation of d-mannose and maltose by acidic solution of N-bromoacetamide
โœ Ashok Kumar Singh; Vineeta Singh; Shahla Rahmani; Ajaya Kumar Singh; Bharat Sing ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 182 KB

The kinetics of the homogeneously Pd(II) catalyzed oxidation of d-mannose (Man) and maltose (Mal) by N-bromoacetamide (NBA) in perchloric acid medium, using mercuric acetate as scavenger for Br -ions as well as co-catalyst, have been studied in the temperature range 35-50 โ€ข C. The reactions exhibit