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Kinetics and mechanism of oxidation of d-glucose and d-ribose by chromium(VI) and vanadium(V) in perchloric acid medium

โœ Scribed by Kalyan Kali Sen Gupta; Samarendra Nath Basu

Book ID
108308639
Publisher
Elsevier Science
Year
1980
Tongue
English
Weight
576 KB
Volume
80
Category
Article
ISSN
0008-6215

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Kinetics and mechanism of oxidation of d
Kinetics and mechanism of oxidation of d-glucopyranose 6-phosphate and d-ribofuranose 5-phosphate by chromium(VI) in perchloric acid media
โœ Kalyan Kali Sen Gupta; Shipra Sen Gupta; Subrata Kumar Mandal; Samarendra Nath B ๐Ÿ“‚ Article ๐Ÿ“… 1985 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 359 KB

The kinetics of oxidation of D-glucopyranose 6-phosphate and D-ribofuranose 5-phosphate by chromium(V1) in perchloric acid media have been studied by U.V. spectroscopy. Each reaction is first order with respect to [chromium(VI)] and [substrate]. The reactions are acid-catalysed and accelerated by th