Kinetics and mechanism of oxidation of uric acid by hexacyanoferrate(III) in acetate buffers
β Scribed by Amita Agrawal; Nidhi Sharma; Som K. Mishra; Prem D. Sharma
- Publisher
- Springer
- Year
- 1992
- Tongue
- English
- Weight
- 390 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0340-4285
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## Abstract The oxidation of halotoluenes by hexacyanoferrate(III) in aqueous acetic acid containing perchloric acid (0.5__M__) at 50Β°C gave the corresponding aldehyde as the major product, and a small amount of polymeric material. The order with respect to each of the reactantsβsubstrate, oxidant,
The kinetics of oxidation of some neutralized β£-hydroxy compounds such as glycolic (GA), lactic (LA), β£-hydroxyisobutyric(IB), mandelic (MA), atrolactic (AL), and benzilic (BA) acids by tetrachloroaurate(III) have been studied. The substrates are oxidized to give formaldehyde, acetaldehyde, acetone,
The hexacyanoferrate(II1)-thallium(1) reaction in aqueous acetic acid containing large concentrations of hydrochloric acid is considerably accelerated both by hydrogen and chloride ions as well as increasing acetic acid in the medium. The experimental results obey the rate law (1) where PI to p6 (1