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Kinetics and mechanism of oxidation of thiocarbohydrazide in the free state and in its metal complex and thiocarbohydrazone by chloramine-T and dichloramine-T

โœ Scribed by B. Thimme Gowda; B. S. Sherigara

Book ID
112906841
Publisher
Indian Academy of Sciences,Royal Society of Chemistry
Year
1989
Tongue
English
Weight
635 KB
Volume
101
Category
Article
ISSN
0253-4134

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Mechanism of oxidations in partially aqu
Mechanism of oxidations in partially aqueous media: Kinetics of oxidation of thiosemicarbazide and thiosemicarbazone by chloramine-T and dichloramine-T in aqueous methanol
โœ B. Thimme Gowda; B. S. Sherigara ๐Ÿ“‚ Article ๐Ÿ“… 1989 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 662 KB

Kinetics of oxidation of thiosemicarbazide (TSC) and its hydrazone (Benzaldehyde thiosemicarbazone) by chloramine-T (CAT) and dichloramine-T (DCT) in aqueous methanol medium in the presence of perchloric acid has been studied. Oxidation of TSC by both the oxidants showed first order dependences in [