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Kinetics and mechanism of oxidation of diols bybis(2,2′-bipyridyl) copper(II) permanganate

✍ Scribed by Kavita Mohnot; Pradeep K Sharma; Kalyan K Banerji

Book ID: 112921571
Publisher: Indian Academy of Sciences,Royal Society of Chemistry
Year: 1996
Tongue: English
Weight: 444 KB
Volume: 108
Category: Article
ISSN: 0253-4134
DOI: 10.1007/bf02871252

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Kinetics and Mechanism of the Oxidation of Organic Sulfides by Bis(2,2' -bipyridyl)copper(II) Permanganate. -The H+-catalyzed oxidation of sulfides to sulfoxides using the title oxidant (BBCP) is found to be first order with respect to BBCP. Michaelis-Menten type kinetics are observed for the sulfi