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Kinetic study of oxidation of some thioacids bybis(2,2′-bipyridyl) copper(II) permanganate

✍ Scribed by Seema Kothari

Book ID: 112919706
Publisher: Indian Academy of Sciences,Royal Society of Chemistry
Year: 1991
Tongue: English
Weight: 224 KB
Volume: 103
Category: Article
ISSN: 0253-4134
DOI: 10.1007/bf02867328

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Kinetics and Mechanism of the Oxidation of Organic Sulfides by Bis(2,2' -bipyridyl)copper(II) Permanganate. -The H+-catalyzed oxidation of sulfides to sulfoxides using the title oxidant (BBCP) is found to be first order with respect to BBCP. Michaelis-Menten type kinetics are observed for the sulfi