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Kinetics and mechanism of Os(VIII) catalyzed oxidation of dimethyl sulfoxide by vanadium(V)

✍ Scribed by Krishna Rao, K. ;Komuraiah, A. ;Hari Kishan, B.

Book ID
112686618
Publisher
Springer
Year
1995
Tongue
English
Weight
251 KB
Volume
54
Category
Article
ISSN
0133-1736

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πŸ“œ SIMILAR VOLUMES

Kinetics and mechanism of oxidation of d
Kinetics and mechanism of oxidation of dimethyl sulfoxide by chloramine-T in aqueous solution
✍ D. S. Mahadevappa; M. B. Jadhav; H. M. K. Naidu πŸ“‚ Article πŸ“… 1979 πŸ› John Wiley and Sons 🌐 English βš– 569 KB

## Abstract The kinetics of oxidation of dimethyl sulfoxide (DMSO) by chloramine‐T (CAT) is studied in HClO~4~ and NaOH media with OsO~4~ as a catalyst in the latter medium. In acid medium, the rate law is ‐__d__ [CAT]/__dt__ = __k__ [CAT][DMSO][H^+^]. Alkali retards the reaction and the rate law t