𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Kinetics and mechanism of oxidation of dimethyl sulfoxide by N-bromoacetamide

✍ Scribed by Venkateshwarlu, S. ;Jagannadham, V.

Book ID
112686239
Publisher
Springer
Year
1985
Tongue
English
Weight
275 KB
Volume
27
Category
Article
ISSN
0133-1736

No coin nor oath required. For personal study only.

πŸ“œ SIMILAR VOLUMES

Kinetics and mechanism of oxidation of d
Kinetics and mechanism of oxidation of dimethyl sulfoxide by chloramine-T in aqueous solution
✍ D. S. Mahadevappa; M. B. Jadhav; H. M. K. Naidu πŸ“‚ Article πŸ“… 1979 πŸ› John Wiley and Sons 🌐 English βš– 569 KB

## Abstract The kinetics of oxidation of dimethyl sulfoxide (DMSO) by chloramine‐T (CAT) is studied in HClO~4~ and NaOH media with OsO~4~ as a catalyst in the latter medium. In acid medium, the rate law is ‐__d__ [CAT]/__dt__ = __k__ [CAT][DMSO][H^+^]. Alkali retards the reaction and the rate law t