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Kinetics and Mechanism of Iron(III)−Nitrilotriacetate Complex Reactions with Phosphate and Acetohydroxamic Acid

✍ Scribed by Gabričević, Mario; Crumbliss, Alvin L.


Book ID
120418005
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
90 KB
Volume
42
Category
Article
ISSN
0020-1669

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Kinetics and mechanism of oxidation of n
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Diperiodatoargentate(III) oxidizes nitrilotriacetic acid in a mildly basic medium to produce formaldehyde and ammonia. This reaction follows a complex kinetic behaviour. The axial binding of NTA to silver(III) complex takes place on the millisecond time-scale with a second-order rate constant of (4.