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Kinetics and Mechanism of Complex Formation Reactions in the Iron(III)−Phosphate Ion System at Large Iron(III) Excess. Formation of a Tetranuclear Complex

✍ Scribed by Lente, Gábor; Magalhães, M. Elizabeth A.; Fábián, István


Book ID
120522541
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
108 KB
Volume
39
Category
Article
ISSN
0020-1669

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## Abstract The results of comprehensive equilibrium and kinetic studies of the iron(III)–sulfate system in aqueous solutions at I = 1.0 M (NaClO~4~), in the concentration ranges of __T__ = 0.15–0.3 mM, and at pH 0.7–2.5 are presented. The iron(III)–containing species detected are FeOH^2+^ (=FeH~−1