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Kinetics and Mechanism of Formation of Yttrium Alkyl Complexes from (Cp* 2 YH) 2 and Alkenes

✍ Scribed by Casey, Charles P.; Tunge, Jon A.; Lee, Ting-Yu; Carpenetti, Donald W.


Book ID
126820031
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
112 KB
Volume
21
Category
Article
ISSN
0276-7333

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## Abstract **Caught in the act**: An alkyl alkene Zr^IV^ complex (see picture; Cp=C~5~H~5~) has been synthesized and characterized for the first time. The alkene bonding mode is highly asymmetric, and C2 is quite carbocationic. There is also evidence for rotation about the C1ο£ΏC2 bond. This extreme