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Structures and Properties of Nonchelated, d0 Alkyl Alkene Complexes of the Type [Cp2ZrMe(alkene)]+: Elusive Intermediates during Ziegler–Natta Polymerizations of Alkenes

✍ Scribed by Francoise Sauriol; Elizabeth Wong; Angela M. H. Leung; Irja Elliott Donaghue; Michael C. Baird; Tebikie Wondimagegn; Tom Ziegler

Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
282 KB
Volume
121
Category
Article
ISSN
0044-8249

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Structures and Properties of Nonchelated
Structures and Properties of Nonchelated, d0 Alkyl Alkene Complexes of the Type [Cp2ZrMe(alkene)]+: Elusive Intermediates during Ziegler–Natta Polymerizations of Alkenes
✍ Francoise Sauriol; Elizabeth Wong; Angela M. H. Leung; Irja Elliott Donaghue; Mi 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 282 KB

## Abstract **Caught in the act**: An alkyl alkene Zr^IV^ complex (see picture; Cp=C~5~H~5~) has been synthesized and characterized for the first time. The alkene bonding mode is highly asymmetric, and C2 is quite carbocationic. There is also evidence for rotation about the C1C2 bond. This extreme