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Kinetics and mechanism of electron-transfer reactions: ruthenium(III) chloride catalyzed oxidation of aspartic acid by peroxomonosulfate ion in acidic medium

✍ Scribed by Riya Sailani; Mridula Sharma; Deepmala Pareek; C. L. Khandelwal; P. D. Sharma

Book ID
113078725
Publisher
Springer-Verlag
Year
2011
Tongue
English
Weight
341 KB
Volume
105
Category
Article
ISSN
1878-5190

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## Abstract Kinetics of uncatalyzed and Ru(III)‐catalyzed oxidations of mono‐, di‐, and tri‐chloroacetic acids by the title compound (bromamine‐B or BAB) in HCl medium has been studied at 40Β°C. The uncatalyzed reaction shows a first‐order dependence of the rate on [BAB], and fractional and zero ord