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Kinetics and Mechanism of Cyclohexanol Dehydration in High-Temperature Water

โœ Scribed by Akiya, Naoko; Savage, Phillip E.


Book ID
120049949
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
103 KB
Volume
40
Category
Article
ISSN
0888-5885

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In the presence of a low concentration (<O.Ol mol dm-3) of sulfuric acid, ethanol undergoes rapid and selective dehydration to ethene in supercritical water. The kinetics of this reaction are consistent with an acid-catalyzed E2 mechanism.