✦ LIBER ✦

Mechanism and kinetics of the acid-catalyzed dehydration of ethanol in supercritical water

✍ Scribed by Xiaodong Xu; Carlos De Almeida; Michael J. Antal Jr.

Publisher: Elsevier Science
Year: 1990
Tongue: English
Weight: 472 KB
Volume: 3
Category: Article
ISSN: 0896-8446
DOI: 10.1016/0896-8446(90)90027-j

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✦ Synopsis

In the presence of a low concentration (<O.Ol mol dm-3) of sulfuric acid, ethanol undergoes rapid and selective dehydration to ethene in supercritical water. The kinetics of this reaction are consistent with an acid-catalyzed E2 mechanism.

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