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Kinetics and mechanism of atrans-tetraazamacrocyclic chromium(III) complex oxidation by hexacyanoferrate(III) in strongly alkaline media

✍ Scribed by Anna Katafias; Olga Impert; Przemysław Kita; Grzegorz Wrzeszcz

Publisher: Springer
Year: 2004
Tongue: English
Weight: 305 KB
Volume: 29
Category: Article
ISSN: 0340-4285
DOI: 10.1007/s11243-004-1568-7

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## Abstract The kinetics of oxidation of sarcosine by diperiodatocuprate(III) (DPC) was studied with spectrophotometry in a temperature range of 292.2–304.2 K. The reaction between diperiodatocuprate(III) and sarcosine in alkaline medium exhibits 1:1 stoichiometry (DPC:sarcosine). The reaction was