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Kinetics and mechanism of a macrocyclic chromium(III) complex oxidation to chromium(IV) by hexacyanoferrate(III) in strongly alkaline media

✍ Scribed by Janusz Chatłas; Olga Impert; Anna Katafias; Przemysław Kita; Grzegorz Wrzeszcz; Jette Eriksen; Ole Mønsted; Andrew Mills

Publisher: Springer
Year: 2004
Tongue: English
Weight: 274 KB
Volume: 29
Category: Article
ISSN: 0340-4285
DOI: 10.1007/s11243-004-4991-x

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## Abstract The kinetics of formation of the [PVA. Mn^VI^O] intermediate complex have been measured by the conventional spectrophotometric technique. The rate of formation of the complex was found to be given by the expression d[Complex]/d__t__ = __k__~1~[MnO‐~4~][PVA^−^]. The results showed that t