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Kinetics and Mechanism for Reduction of Tetrachloroaurate(III), trans-Dicyanodichloraurate(III), and trans-Dicyanodibromoaurate(III) by Sulfite and Hydrogen Sulfite

โœ Scribed by Berglund, Johan; Elding, Lars I.

Book ID
121315266
Publisher
American Chemical Society
Year
1995
Tongue
English
Weight
663 KB
Volume
34
Category
Article
ISSN
0020-1669

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Kinetics and mechanism of the reduction
Kinetics and mechanism of the reduction of tetrachloroaurate(III) by malonate in acidic aqueous solution
โœ B.S. Maritz; R. van Eldik ๐Ÿ“‚ Article ๐Ÿ“… 1976 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 492 KB

The reaction between tetrachloroaurate(III) and malonic acidfmalonate ion was studied kinetically over a wide range of temperatures, malonate, hydrogen and chloride ion concentrations at ionic strength 1.0 M. The suggested reaction mechanism consists of a series of substitution reactions during whic