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Kinetics and mechanism of the reduction of tetrachloroaurate(III) by oxalate in acidic aqueous solution

โœ Scribed by B.S. Maritz; R. Van Eldik

Book ID
114040685
Publisher
Elsevier Science
Year
1976
Tongue
English
Weight
586 KB
Volume
17
Category
Article
ISSN
0020-1693

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Kinetics and mechanism of the reduction
Kinetics and mechanism of the reduction of tetrachloroaurate(III) by malonate in acidic aqueous solution
โœ B.S. Maritz; R. van Eldik ๐Ÿ“‚ Article ๐Ÿ“… 1976 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 492 KB

The reaction between tetrachloroaurate(III) and malonic acidfmalonate ion was studied kinetically over a wide range of temperatures, malonate, hydrogen and chloride ion concentrations at ionic strength 1.0 M. The suggested reaction mechanism consists of a series of substitution reactions during whic