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Kinetic study on radical polymerization with consideration of reversibility of propagation reaction

โœ Scribed by Bunichiro Yamada; Katsuhiko Fukushima; Takayuki Otsu


Book ID
105016048
Publisher
Springer
Year
1981
Tongue
English
Weight
243 KB
Volume
6
Category
Article
ISSN
0170-0839

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The polymerization of diisopropyl itaconate (DIPI) initiated with dimethyl 2,2'-azobisisobutyrate(MAIB) was investigated kinetically in benzene. The polymerization rate (Rp) was expressed by R v = k[MAIB]ยฐ46[I)IPI] 16 at 50 ยฐ. The overall activation energy of the polymerization was calculated to be

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