Kinetic study on radical polymerization with consideration of reversibility of propagation reaction
โ Scribed by Bunichiro Yamada; Katsuhiko Fukushima; Takayuki Otsu
- Book ID
- 105016048
- Publisher
- Springer
- Year
- 1981
- Tongue
- English
- Weight
- 243 KB
- Volume
- 6
- Category
- Article
- ISSN
- 0170-0839
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
The polymerization of diisopropyl itaconate (DIPI) initiated with dimethyl 2,2'-azobisisobutyrate(MAIB) was investigated kinetically in benzene. The polymerization rate (Rp) was expressed by R v = k[MAIB]ยฐ46[I)IPI] 16 at 50 ยฐ. The overall activation energy of the polymerization was calculated to be
Polymerization of 2-methacryloyloxyethyl phosphorylcholine (MPC) was kinetically investigated in ethanol using dimethyl 2,2ะ-azobisisobutyrate (MAIB) as initiator. The overall activation energy of the homogeneous polymerization was calculated to be 71 kJ/mol. The polymerization rate (R p ) was expre
Radical polymerization of dicyclohexyl fumarate (DCHF) initiated with dimethyl 2,2'-azobisisobutyrate (MAIB) or 2,2'-azobisisobutyronitrile (AIBN) at 60 ยฐ was studied kinetically. The polymerization rate (Rp) initiated with MAIB was greater than that with AIBN, in spite of the similar decomposition