Kinetic study of the oxidation of alcohols by cetyltrimethylammonium permanganate
✍ Scribed by Šumichrast, R. ;Holba, V.
- Book ID
- 112686039
- Publisher
- Springer
- Year
- 1992
- Tongue
- English
- Weight
- 186 KB
- Volume
- 48
- Category
- Article
- ISSN
- 0133-1736
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract Cetyltrimethylammonium permanganate (CTAP) has been prepared and characterized from IR and NMR data. At room temperature the compound is stable when kept in dark but at 115°C it undergoes a violent thermal decomposition. In different organic solvents self‐oxidation takes place giving ri
The kinetics of the oxidation of mandelic acid (MA) by permanganate in aqueous alkaline medium at a constant ionic strength of 1.0 mol dm À3 were studied spectrophotometrically. The reaction shows first-order kinetics in [permanganate ion] and fractional order dependences in [MA] and [alkali]. Addit
The kinetics of the reaction between permanganate ion and triethylamine in aqueous phosphate buffers (pH 6-8) has been studied. The reaction is autocatalytic, a soluble form of colloidal manganese dioxide temporarily stabilized in solution by adsorption of phosphate ions on its surface having been i