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Kinetic Study of The Homolytic Substitution in Triethyltinbromide by Photochemically Generated Iodine Atoms

✍ Scribed by L. Verdonck; E. Saccasijn; P. H. De Ryck; S. Hoste; G. P. van Der Kelen

Publisher
Wiley (John Wiley & Sons)
Year
2010
Weight
127 KB
Volume
93
Category
Article
ISSN
0037-9646

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Homolytic substitution in trialkyltin io
Homolytic substitution in trialkyltin iodides by photochemically generated iodine atoms. I. Kinetics
✍ P. H. De Ryck; L. Verdonck; G. P. Van Der Kelen πŸ“‚ Article πŸ“… 1985 πŸ› John Wiley and Sons 🌐 English βš– 488 KB

The kinetics of the homolytic substitution of several trialkyltin iodides by iodine atoms are presented. Rate constants have been determined at three different temperatures and the following activation parameters calculated: A , E,, and AS"'. The observation that the activation energy, AG\*, is rela