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Homolytic Substitution in Trialkyltin Iodides by Photochemically Generated Iodine Atoms. III. Mechanism and thermodynamics

โœ Scribed by P. H. De Ryck; L. Verdonck; G. P. Der Van Kelen

Publisher
Wiley (John Wiley & Sons)
Year
2010
Weight
309 KB
Volume
94
Category
Article
ISSN
0037-9646

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Homolytic substitution in trialkyltin io
Homolytic substitution in trialkyltin iodides by photochemically generated iodine atoms. I. Kinetics
โœ P. H. De Ryck; L. Verdonck; G. P. Van Der Kelen ๐Ÿ“‚ Article ๐Ÿ“… 1985 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 488 KB

The kinetics of the homolytic substitution of several trialkyltin iodides by iodine atoms are presented. Rate constants have been determined at three different temperatures and the following activation parameters calculated: A , E,, and AS"'. The observation that the activation energy, AG\*, is rela