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Homolytic substitution in trialkyltin iodides by photochemically generated iodine atoms: II. Mechanistic interpretation

โœ Scribed by L. Verdonck; P.H. De Ryck; S. Hoste; O.P. Van der Kelen


Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
384 KB
Volume
288
Category
Article
ISSN
0022-328X

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Homolytic substitution in trialkyltin io
โœ P. H. De Ryck; L. Verdonck; G. P. Van Der Kelen ๐Ÿ“‚ Article ๐Ÿ“… 1985 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 488 KB

The kinetics of the homolytic substitution of several trialkyltin iodides by iodine atoms are presented. Rate constants have been determined at three different temperatures and the following activation parameters calculated: A , E,, and AS"'. The observation that the activation energy, AG\*, is rela