CFBr radicals produced by the reaction of atomic oxygen with FzCCFBr were monitored in a discharge flow system by fluorescence excited at 424 nm. The rate coefficients for reactions of the CFBr radicals were measured between 298 and 358 K, and the following values were obtained in units of cm3/molec
Kinetic Study of the CCl 2 Radical Recombination Reaction by Laser-Induced Fluorescence Technique
✍ Scribed by Gómez, Nicolás D.; D'Accurso, Violeta; Freytes, V. Mariana; Manzano, Francisco A.; Codnia, Jorge; Azcárate, M. Laura
- Book ID
- 120176427
- Publisher
- John Wiley and Sons
- Year
- 2013
- Tongue
- English
- Weight
- 484 KB
- Volume
- 45
- Category
- Article
- ISSN
- 0538-8066
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Iser-based clwmicsl kinetics technique has been demonstrated in studies of the reaction of 011 with C2114\_ The rcxtwn mcchnism is dominated by elcctrophtlic addition of OH to the double bond at low temperatures, and by increasing-I\ rApid decomposition of the thcrmalized adduct iiOC2t-l.~ back to r
## Abstract The laser photolysis‐laser‐induced fluorescence method was used for measuring the kinetic parameters of the reaction of OH radicals with CF~3~CH~2~OCH~2~CF~3~ (2,2,2‐trifluoroethyl ether), in the temperature range of 298–365 K. The bimolecular rate coefficient at 298 K, __k__~II~(298),
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