Kinetic Study of the C 10 H 7 + O 2 Reaction
β Scribed by Park, J.; Xu, Z. F.; Lin, M. C.
- Book ID
- 125893258
- Publisher
- American Chemical Society
- Year
- 2009
- Tongue
- English
- Weight
- 330 KB
- Volume
- 113
- Category
- Article
- ISSN
- 1089-5639
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π SIMILAR VOLUMES
The rate coefficients for the gas-phase reactions of C,H,O;, and n-C3H,0, radicals with NO have been measured over the temperature range of (201 -403) K using chemical ionization mass spectrometric detection of the peroxy radical. The alkyl peroxy radicals were generated by reacting alkyl radicals w
The overall rate constant for the reaction between ethylperoxy radicals and nitric oxide has been directly measured by flash photolysis and kinetic spectroscopy. At room temperature the rate constant k 7 = (1.6\* 0.1) X 10' litremole-' F' has been assigned to the reaction C2H502 + NO + CzHsO + NO\*\
## Abstract The reaction of H radical with C~2~H~5~CN has been studied using various quantum chemistry methods. The geometries were optimized at the B3LYP/6β311+G(d,p) and B3LYP/6β311++G(2d,2p) levels. The singleβpoint energies were calculated using G3 and BMCβCCSD methods based on B3LYP/6β311++G(2
The reaction between CzH5 and 0 2 a t 295 K has been studied with a flow reactor sampled by a mass spectrometer. With helium as the carrier gas the rate coefficient was found to increase from (1.2 f 0.3) X cm3/s as [He] was increased from 2 X 10I6 to 3.4 X 1017 The importance of to (3.6 f 0.9) has