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Kinetic study of ruthenium(VI) -- catalyzed oxidation of 2-methoxy- ethanol by aqueous alkaline hexacyanoferrate(III)

✍ Scribed by Veena; K. Behari


Book ID
106547225
Publisher
Springer
Year
2007
Tongue
English
Weight
209 KB
Volume
32
Category
Article
ISSN
0340-4285

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Kinetic study of ruthenium (VI)-catalyze
✍ A. E. Mucientes; F. J. Poblete; M. A. RodrΓ­guez; F. Santiago πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 English βš– 101 KB πŸ‘ 2 views

The kinetics of Ru(VI)-catalyzed oxidation of 2-propanol by hexacyanoferrate(III) was investigated in alkaline media using a spectrophotometric technique. The reaction shows first order in [Ru(VI)], a Michaelis-Menten-type dependence on [2-propanol], a fractional order in [Fe(CN) 3Γ€ 6 ] and a compli

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The oxidation kinetics of 2-butanol by alkaline hexacyanoferrate(III) catalyzed by sodium ruthenate has been studied spectrophotometrically. The initial rates method was used for kinetic analysis. The reaction rate shows a fractional-order in [hexacyanoferrate(III)] and [substrate] and a first-order

Kinetic study of the ruthenium(VI)-catal
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## Abstract The kinetics of the Ru(VI)‐catalyzed oxidation of benzyl alcohol by hexacyanoferrate(III), in an alkaline medium, has been studied using a spectrophotometric technique. The initial rates method was used for the kinetic analysis. The reaction is first order in [Ru(VI)], while the order c

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The kinetics of the oxidation of cyclopentanol, cyclohexanol, 2-methylcyclohexanol, and cycloheptanol by hexacyanoferrate(II1) ions in mild alkaline medium has been studied in the presence of traces of ruthenium(V1) = lO-?M at constant ionic strength (0.26M). The results suggest that the oxidation o