The kinetics of Ru(VI)-catalyzed oxidation of 2-propanol by hexacyanoferrate(III) was investigated in alkaline media using a spectrophotometric technique. The reaction shows first order in [Ru(VI)], a Michaelis-Menten-type dependence on [2-propanol], a fractional order in [Fe(CN) 3Γ 6 ] and a compli
Ruthenium(VI)-catalysed oxidation of diols by alkaline hexacyanoferrate(III) ion. A kinetic study
β Scribed by Kunj Behari; Roli Srivastava
- Book ID
- 110244805
- Publisher
- Springer
- Year
- 1998
- Tongue
- English
- Weight
- 93 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0340-4285
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π SIMILAR VOLUMES
The oxidation kinetics of 2-butanol by alkaline hexacyanoferrate(III) catalyzed by sodium ruthenate has been studied spectrophotometrically. The initial rates method was used for kinetic analysis. The reaction rate shows a fractional-order in [hexacyanoferrate(III)] and [substrate] and a first-order
## Abstract The kinetics of the Ru(VI)βcatalyzed oxidation of benzyl alcohol by hexacyanoferrate(III), in an alkaline medium, has been studied using a spectrophotometric technique. The initial rates method was used for the kinetic analysis. The reaction is first order in [Ru(VI)], while the order c