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Ruthenium(VI)-catalysed oxidation of diols by alkaline hexacyanoferrate(III) ion. A kinetic study

✍ Scribed by Kunj Behari; Roli Srivastava


Book ID
110244805
Publisher
Springer
Year
1998
Tongue
English
Weight
93 KB
Volume
23
Category
Article
ISSN
0340-4285

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The kinetics of Ru(VI)-catalyzed oxidation of 2-propanol by hexacyanoferrate(III) was investigated in alkaline media using a spectrophotometric technique. The reaction shows first order in [Ru(VI)], a Michaelis-Menten-type dependence on [2-propanol], a fractional order in [Fe(CN) 3Γ€ 6 ] and a compli

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## Abstract The kinetics of the Ru(VI)‐catalyzed oxidation of benzyl alcohol by hexacyanoferrate(III), in an alkaline medium, has been studied using a spectrophotometric technique. The initial rates method was used for the kinetic analysis. The reaction is first order in [Ru(VI)], while the order c