Kinetic study of dimethylsulfide and methanethiol synthesis
β Scribed by V.Yu. Mashkin
- Book ID
- 103965499
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- English
- Weight
- 899 KB
- Volume
- 109
- Category
- Article
- ISSN
- 0926-860X
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π SIMILAR VOLUMES
The kinetics and mechanism of the reaction of BrO with dimethylsulfide [ DMS) have been studied by the mass spectrometric discharge-flow method in the temperature range (233-320) K and at a total pressure around 1 torr. The temperature dependence of the reaction rate constant k , = [ 1.5 ? 0 4 ) X 1
The kinetics of the reactions of 10, BrO, and C10 with DMS have been investigated at 298 K and total pressures of 0.5-6.8 mbar He using the discharge flow-mass spectrometry technique to monitor the halogen oxide radicals. Rate coefficients of (8.8 (2.7 f 0.5) x cm3 molecule-' 8-l have been obtained