Kinetic Studies on the Reactions of Hydroxyl Radicals with Cyclic Ethers and Aliphatic Diethers
โ Scribed by Moriarty, Jennie; Sidebottom, Howard; Wenger, John; Mellouki, Abdelwahid; Le Bras, Georges
- Book ID
- 127255503
- Publisher
- American Chemical Society
- Year
- 2003
- Tongue
- English
- Weight
- 107 KB
- Volume
- 107
- Category
- Article
- ISSN
- 1089-5639
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
Rate coefficients for OH reactions with the 2-5 carbon aliphatic aldehydes have been measured under pseudo first-order conditions in OH. OH was generated by flash photolysis of H 2 0 a t wavelengths greater than 165 nm and its concentration monitored using time-resolved resonance fluorescence spectr
Absolute rate coeficients for the reactions of the hydroxyl radical with dimethyl ether i k , ) and diethyl ether ( k 2 ) were measured over the temperature range 295-442 K. The rate coefficient data, in the units cm3 molecule s-l, were fitted to the Arrhenius equationsk,(T) = (1.04 2 0.10) x 10-"ex