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Kinetics of the reactions of hydroxyl radicals with aliphatic ethers studied under simulated atmospheric conditions: Temperature dependences of the rate coefficients

✍ Scribed by Paul J. Bennett; J. Alistair Kerr

Publisher: Springer Netherlands
Year: 1990
Tongue: English
Weight: 543 KB
Volume: 10
Category: Article
ISSN: 0167-7764
DOI: 10.1007/bf01980036

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The rate constant for the gas-phase reaction of the hydroxyl radical with trifluoroacetic acid has been determined over the temperature range 283-323 K using a relative rate technique. The results provide a value of k( OH+CF,C(O)OH) = 2.O~lO-\*~exp(-l46~500/T)cm~molecule~'s-'basedonk(OH+C~H,)=7.8~lO