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Kinetic studies on the mechanism of the decomposition of a number of β-substituted tert -butyl α, α -dimethylperpropionates

✍ Scribed by Tanner, Dennis D.; Yabuuchi, H.; Lutzer, H.


Book ID
121347515
Publisher
NRC Research Press
Year
1977
Tongue
French
Weight
306 KB
Volume
55
Category
Article
ISSN
0008-4042

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✍ Nadejda Reikonnen; Ignacio Martin; Gabriel Chuchani; Jacek Lubinkowski 📂 Article 📅 1985 🏛 John Wiley and Sons 🌐 English ⚖ 314 KB 👁 1 views

## Abstract The gas‐phase eliminations of several __tert__‐butyl esters, in a static system and in vessels seasoned with allyl bromide, have been studied in the temperature range of 171.5–280.1°C and the pressure range of 23–98 torr. The rate coefficients for the homogeneous unimolecular eliminatio