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Addition of tert-Butyl Radical to Substituted Alkenes: A Theoretical Study of the Reaction Mechanism

✍ Scribed by Wong, Ming Wah; Pross, Addy; Radom, Leo

Book ID
126180822
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
790 KB
Volume
116
Category
Article
ISSN
0002-7863

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## Abstract The radical‐radical reaction mechanisms and dynamics of ground‐state atomic oxygen [O(^3^P)] with the saturated __tert__‐butyl radical (__t__‐C~4~H~9~) are investigated using the density functional method and the complete basis set model. Two distinctive reaction pathways are predicted